Battery In-situ IR Accessory

Figure 1: In situ electrochemical infrared attachments to lithium ion batteries
Electrochemical infrared spectrum analysisIt is an important branch of infrared analysis technology, capable of qualitative analysis of electrical catalyticization. Like CO2The changing trend of electro-regressive reactions, products or intermediates of electrode surfaces during charging of various types of batteries (e.g. lithium ion, lithium sulphur batteries, etc.) over time is one of the important means of studying electrochemical reaction mechanisms and electrochemical reaction dynamics.
Construct principles:
(1) A bipolar system specially designed for battery systems.
(2) The electrochemical reaction pool is of good gas density and has access to the reaction gas.
(3) Diamond crystals, widely applicable.


Figure 2: Outline of the rationale
Composition of the annex
(1) The Infrared Spectrometer (IR spectrometer) hosts adapt to the base plate and to the mainstream infrared spectrometer.
(2) Photo-routing systems.
(3) PEEK materials, gas-intensive electrochemical ponds.
(4) Type O loop seal.
Main features
(1) Optimized light-routing systems with high light flux.
(2) Electrochemical ponds are in a good state of containment and can reach reaction gases.
(3) The flux of crystals of diamonds is significant.
(4) Unique electrodes, electrolytic signal collection and control techniques.
(5) Triple use of electrochemical infrared spectrometers can be achieved.
(6) Diamond crystal plates and electrochemical ponds can be removed and batteries can be assembled in glove boxes.
(7) Provide on-site technical services.
Main technical parameters
1Spectrum range: 250/525-4000 cm-1
Crystal type: Diamond crystal
3. Electrochemical ponds: PEEK materials, bipolar systems, gas-enrichment ponds, easy handling of batteries in glove boxes, vents and vents for infrared spectroscopy collection during battery charging.
4. Temperature control electrochemical pool, temperature control range: RT-100°C, temperature control accuracy 0.1°C.
5. The electrodes and diamond crystals distance adjustment system, with a calibration fine-tuning function and a good recurrence to allow observation of electrolytic solvents or changes in electrode surface species.
6. The electrochemical pool can be used in combination with the IR spectrometer to provide multi-channel technology programmes.
7. Number of reflections: a single reflection.
8. Reflection type: external reflection.
9. The optical reflector system adapts to the mainstream brand-named infrared spectrometer, which provides the spectrometer adaptor base plate, and the optical system facilitates the placement or extraction of the spectrometer sample warehouse.
Application cases

Lithium ion batteries Chem. Mater. 2020, 32, 8, 3405–3413

Lithium ion batteries ACS Energy Lett. 2020, 5, 1022- 1031

Zinc ion batteries Adv. Funct. Mater. 2020, 2003890

Lithium ion batteries Joule 2022, 6, 399–417
Selected client papers publishedSingle:
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Jianping Xiao*, Bin Zhang*, et al. Unveiling hydrocerussite as an electrochemically stable active phase for efficient carbon dioxide electroreduction to formate. Nat. Commun. 2020, 11, 3415
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Lei Yan, Yonggang Wang*, et al. Chemically Self-Charging Aqueous Zinc-Organic Battery. J. Am. Chem. Soc. 2021, 143, 15369-15377
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Bingliang Wang, Yongyao Xia*, et al. In situ structural evolution of the multi-site alloy electrocatalyst to manipulate the intermediate for enhanced water oxidation reaction. Energy Environ. Sci. 2020, 13, 2200-2208
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Yang Peng*, et al. Breaking Linear Scaling Relationship by Compositional and Structural Crafting of Ternary Cu-Au/Ag Nanoframes for Electrocatalytic Ethylene Production. Angew. Chem. Int. Ed. 2021, 60, 2508-2518
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Zhuo Yu, Yonggang Wang*, et al. Boosting Polysulfide Redox Kinetics by Graphene-Supported Ni Nanoparticles with Carbon Coating. Adv. Energy Mater. 2020, 10, 2000907
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Xinwei Ding, Zhi Yang*, et al. Biomimetic Molecule Catalysts to Promote the Conversion of Polysulfides for Advanced Lithium–Sulfur Batteries Adv. Funct. Mater. 2020, 30, 2003354
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Hong Guo*, Xueliang Sun*, et al. Dual Active Site of the Azo and Carbonyl-Modified Covalent Organic Framework for High-Performance Li Storage. ACS Energy Lett. 2020, 5, 1022-1031
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Bin Zhang* et al. Superficial Hydroxyl and Amino Groups Synergistically Active Polymeric Carbon Nitride for CO2 Electroreduction. ACS Catal. 2019, 9, 10983-10989
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Suya Zhou, Zhi Yang*, et al. Dual-Regulation Strategy to Improve Anchoring and Conversion of Polysulfides in Lithium–Sulfur Batteries ACS Nano. 2020, 14, 7538–7551
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Yongyao Xia*, et al. Low-Temperature Charge/Discharge of Rechargeable Battery Realized by Intercalation Pseudocapacitive Behavior. Adv. Sci. 2020, 7, 2000196
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Lei Wang*, Yonggang Wang, et al. Pencil-drawing on nitrogen and sulfur co-doped carbon paper: An effective and stable host to pre-store Li for high-performance lithium–air batteries. Energy Storage Materials. 2020, 26, 593-603
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Bin Zhang, et al. Unveiling in situ evolved In/In2O3− x heterostructure as the active phase of In2O3 toward efficient electroreduction of CO2 to formate. Science Bulletin. 2020, 65, 1547-1554
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Huani Li, Shubiao Xia*, Hong Guo*, et al. Red Phosphorus Confined in Hierarchical Hollow Surface-Modified Co9S8 for Enhanced Sodium Storage. Sustainable Energy Fuels. 2020, 4, 2208-2219
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Guanglei Cui*, Liquan Chen, et al. Non-flammable nitrile deep eutectic electrolyte enables high voltage lithium metal batteries. Chem. Mater. 2020, 32, 3405-3413
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Guanglei Cui*, et al. Investigation on the Cathodic Interfacial Stability of Nitrile Electrolyte and its performance with High Voltage LiCoO2 Chem. Commun. 2020, 56, 4998-5001
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Zhongbin Zhuang*, et al. A highly-active, stable and low-cost platinum-free anode catalyst based on RuNi for hydroxide exchange membrane fuel cells. Nat. Commun. 2020, 11, 5651
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Tiancun Liu, Yong Wang*, et al. Organic supramolecular protective layer with rearranged and defensive Li deposition for stable and dendrite-free lithium metal anode. Energy Storage Materials. 2020, 32, 261–271
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X. Yin, Y. Wang*, et al. Designing cobalt-based coordination polymers for high-performance sodium and lithium storage: from controllable synthesis to mechanism detection. Materials Today Energy. 2020, 17, 100478
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Song Chen, Jintao Zhang*, et al. Regulation of Lamellar Structure of Vanadium Oxide via Polyaniline Intercalation for High-Performance Aqueous Zinc-Ion Battery. Adv. Funct. Mater. 2020, 30, 2003890
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Yanrong Xue, Zhongbin Zhuang*, et al. Sulfate-Functionalized RuFeOx as Highly Efficient Oxygen Evolution Reaction Electrocatalyst in Acid. Adv. Funct. Mater. 2021, 31, 2101405
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Hong Guo*, et al. Cooperative catalytic interface accelerates redox kinetics of sulfur species for high-performance Li-S batteries. Energy Storage Materials. 2021, 40, 139-149
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Bin Zhang*, et al. Promoting nitric oxide electroreduction to ammonia over electron-rich Cu modulated by Ru doping. SCIENCE CHINA Chemistry. 2021, 64, 1493–1497
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Yang Peng*, et al. Geometric Modulation of Local CO Flux in Ag@Cu2O Nanoreactors for Steering the CO2RR pathway toward High-Efficacy Methane Production. Adv. Mater. 2021, 33, 2101741
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Yonggang Wang*, et al. Molecular Tailoring of n/p-type Phenothiazine Organic Scaffold for Zinc Batteries. Angew. Chem. Int. Ed. 2021, 60, 20826-20832
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Hongliang Jiang*, Chunzhong Li*, et al. Dynamically Formed Surfactant Assembly at the Electrified Electrode–Electrolyte Interface Boosting CO2 Electroreduction. J. Am. Chem. Soc. 2022, 144, 6613–6622
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Yang Peng*, et al. Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production. Nat. Commun. 2022, 13, 63
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Jie Zeng*, et al. Copper-catalysed exclusive CO2 to pure formic acid conversion via single-atom alloying. Nature Nanotechnology. 2021, 16, 1386-1393
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Min-Rui Gao*, et al. Identification of Cu(100)/Cu(111) Interfaces as Superior Active Sites for CO Dimerization During CO2 Electroreduction. J. Am. Chem. Soc. 2022, 144, 1, 259-269
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Chen Feng, Shiming Zhou*, Jie Zeng*, et al. Tuning the Electronic and Steric Interaction at the Atomic Interface for Enhanced Oxygen Evolution. J. Am. Chem. Soc. 2022, 144,21,9271-9279
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Rui Lin, Jianhui Wang, et al. Asymmetric donor-acceptor moleculeregulated core-shell-solvation electrolyte for high-voltage aqueous batteries. Joule 2022, 6, 399–417
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Xiaogang Zhang*, et al. Successive Cationic and Anionic (De)-Intercalation/Incorporation into an Ion-Doped Radical Conducting Polymer. Batteries & Supercaps 2019, 2, 979-984
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Zhongju Wang, Yongzhu Fu*, et al. Biredox‐Ionic Anthraquinone‐Coupled Ethylviologen Composite Enables Reversible Multielectron Redox Chemistry for Li‐Organic Batteries. Adv. Sci. 2022, 9, 2103632
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Jintao Zhang*, et al. Defect evolution of hierarchical SnO2 aggregatesfor boosting CO2 electrocatalytic reduction. J. Mater. Chem. A 2021, 9, 14741-14751
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Fei Ai, Yijun Lu*, et al. Heteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures. Nature Energy 2022, 7, 417–426
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Zhejun Li, Yijun Lu*. Polysulfide-based redox flow batteries with long life and low levelized cost enabled by charge-reinforced ion-selective membranes. Nature Energy 2021, 6, 517–528
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Shanshan Lu, Wei Zhou. et al. Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution. Chem. 2022, 8, 1415-1426.
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Tieliang Li, Yifu Yu, Bin Zhang*, et al. Sulfate-Enabled Nitrate Synthesis from Nitrogen Electrooxidation on Rhodium Electrocatalyst. Angew. Chem. Int. Ed. 2022, e202204541
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Yanbo Li, Bin Zhang, Yifu Yu*, et al. Electrocatalytic Reduction of Low-Concentration Nitric Oxide into Ammonia over Ru Nanosheets. ACS Energy Letters 2022, 7, 1187-1194
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Yanmei Huang, Yifu Yu, Bin Zhang*, et al. Direct Electrosynthesis of Urea from Carbon Dioxide and Nitric Oxide. ACS Energy Letters 2022, 7, 284-291
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Wenfu Xie, Hao Li, Min Wei*, et al. NiSn Atomic Pair on Integrated Electrode for Synergistic Electrocatalytic CO2 Reduction. Angew. Chem. Int. Ed. 2021, 60, 7382–7388
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Rui Sui, Jiajing Pei, Zhongbin Zhuang*, et al. Engineering Ag−Nx Single-Atom Sites on Porous Concave N-Doped Carbon for Boosting CO2 Electroreduction. ACS Appl. Mater. Interfaces 2021, 13, 17736-17744
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Tiliang Li, Yuting Wang, Yifu Yu*, Bin Zhang*, et al. Ru-Doped Pd Nanoparticles for Nitrogen Electrooxidation to Nitrate. ACS Catal. 2021, 11, 14032-14037
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Bin Zhang*, et al. Promoting selective electroreduction of nitrates to ammonia over electron-deficient Co modulated by rectifying Schottky contacts. Science China Chemistry 2020, 63, 1469-1476
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Jiangwei Shi, Bin Zhang*, et al. Promoting nitric oxide electroreduction to ammonia over electron-rich Cu modulated by Ru doping. Science China Chemistry 2021, 64, 1493-1497
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Jintao Zhang* et al. Atomic Bridging Structure of Nickel-Nitrogen-Carbon for Highly Efficient Electrocatalytic Reduction of CO2. Angew. Chem.Int. Ed. 2022, 61, e202113918
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Lang Xu* et al. Gadolinium Changes the Local Electron Densities of Nickel 3d Orbitals for Efficient Electrocatalytic CO2 Reduction. Angew. Chem.Int. Ed. 2022, 61, e202201166
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Bin Zhang* et al. Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution. Chem. 2022, 8, 1415-1426
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Sheng Dai*, Minghui Zhua*, Yifan Han* et al. Probing the role of surface hydroxyls for Bi, Sn and In catalysts during CO2 Reduction. Applied Catalysis B: Environmental 2021, 298,
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Nan Wang, Yonggang Wang*, et al. Zinc-organic Battery with a Wide Operation-temperature Window from -70 to 150 oC. Angew. Chem. Int. Ed. 2020,59,14577-14583
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Nannan Meng, Yifu Yu, Bin Zhang*, et al. Efficient Electrosynthesis of Syngas with Tunable CO/H2 Ratios over ZnxCd1-xS-Amine Inorganic-Organic Hybrids. Angew. Chem. Int. Ed. 2019, 58, 18908–18912
